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Stereoselective Synthesis of Syn,Syn- and Syn,Anti-1,3,5-Triols via Intramolecular Hydrosilylation of Substituted Pent-3-en-1,5-diols
[Image: see text] A stereoselective method for synthesis of syn,syn- and syn,anti-1,3,5-triols based on a double allylboration-intramolecular hydrosilylation sequence has been developed. 1,3-Syn stereocontrol is achieved in the intramolecular hydrosilylation of mono-protected (Z)-1,5-syn-diols and (...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2009
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2755244/ https://ncbi.nlm.nih.gov/pubmed/19507846 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9009877 |
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