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Stereoselective Construction of all-anti Polypropionate Modules: Synthesis of the C5-C10 Fragment of Streptovaricin U

[Image: see text] A concise non-aldol approach for the stereoselective construction of all-anti polypropionate fragments was developed. The iterative epoxide-based methodology consists of the syn-selective epoxidation of cis homoallylic alcohols using the VO(acac)(2) catalyzed conditions followed by...

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Bibliographic Details
Main Authors: Torres, Wildeliz, Rodríguez, Raúl R., Prieto, José A.
Format: Artigo
Language:Inglês
Published: 2009
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2677810/
https://ncbi.nlm.nih.gov/pubmed/19236033
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo8026966
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