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Acyclic 1,4-Stereocontrol via Reductive 1,3-Transpositions
[Image: see text] One-pot reduction/allylic diazene rearrangement of lactic and mandelic acid-derived α,β-unsaturated tosyl hydrazones leads to 1,4-syn- or 1,4-anti-E-2-alkenyl arrays in high yield and diastereoselectivity. Either the syn or the anti diastereomer can be prepared by choosing the appr...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2007
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2613761/ https://ncbi.nlm.nih.gov/pubmed/18092798 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol702921x |
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