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Solvolysis of a Tetrahydropyranyl Mesylate: Mechanistic Implications for the Prins Cyclization, 2-Oxonia-Cope Rearrangement, and Grob Fragmentation
A solvolysis reaction is used to demonstrate that a tetrahydropyranyl cation is a common intermediate for Prins cyclizations, 2-oxonia Cope rearrangements, and Grob fragmentations of tetrahydropyran rings.
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2487678/ https://ncbi.nlm.nih.gov/pubmed/16671810 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0606738 |
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