Application of the Aza-Achmatowicz Oxidative Rearrangement for the Stereoselective Synthesis of the Cassia and Prosopis Alkaloid Family

cis-2-Methyl-6-substituted piperidin-3-ol alkaloids of the Cassia and Prosopis species are readily prepared by a combination of an aza-Achmatowicz oxidative rearrangement, dihydropyridone reduction followed by a Stereoselective allylsilane addition to a N-sulfonyliminium ion. The stereochemical outc...

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Bibliographic Details
Main Authors: Leverett, Carolyn A., Cassidy, Michael P., Padwa, Albert
Format: Artigo
Language:Inglês
Published: 2006
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2475587/
https://ncbi.nlm.nih.gov/pubmed/17064038
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo0616714
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