Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates

We report herein a facile Hiyama cross-coupling reaction of arylsilanes with thiuram reagents (tetraalkylthiuram disulfides or tetraalkylthiuram monosulfide) enabled by copper fluoride. Compared to our previous work, this protocol is an alternative protocol for the generation of S-aryl dithiocarbama...

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Hauptverfasser: Yiying Wang, Hongtao Shen, Jianhua Qiu, Mengqi Chen, Weimin Song, Mingqin Zhao, Longfei Wang, Feng Bai, Hongxia Wang, Zhiyong Wu
Format: Artigo
Sprache:Inglês
Veröffentlicht: Frontiers Media S.A. 2022-04-01
Schriftenreihe:Frontiers in Chemistry
Schlagworte:
Hiyama cross-coupling
arylsilanes
thiuram reagents
C-S bond formation
aryl dithiocarbamates
Online Zugang:https://www.frontiersin.org/articles/10.3389/fchem.2022.867806/full
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